poptartxkilla
This was an 'answer the question from Yedda' . . . if I am reading your question correctly, could this be the answer you need? Just click on any of the 'boxes' and that will redirect you to a site specific for chemestry. Perhaps you can find an answer. Unfortunately, there is no format that allows me to enter the ratio involved.
The effects of oxygen limitation on solid-bed bioleaching of heavy metals (Me) were studied in a laboratory percolator system using contaminated sediment supplemented with 2% elemental sulfur (So). Oxygen limitation was realized by controlling the gas flow and oxygen concentration in the aeration gas. The oxygen supply varied between 150 and
over 28 d of leaching. Moderate oxygen limitation led to temporarily suppression of acidification, rate of sulfate generation and Me solubilization. Lowering the oxygen supply to
resulted in retarding acidification over a period of three weeks and in poor Me solubilization. Oxidation of So occurred even under strong oxygen limitation at a low rate. High surplus of oxygen was necessary for almost complete oxidation of the added So. The maximum Me solubilization was reached at an oxygen supply of
. Thus, the oxygen input during solid-bed bioleaching can be reduced considerably by controlling the gas flow without loss of metal removal efficiency. Oxygen consumption rates, ranging from 0.4 × 10?8 to
, are primarily attributed to high reactivity of the sulfur flower and high tolerance of indigenous autotrophic bacteria to low oxygen concentrations. The So related oxygen consumption was calculated assuming a molar yield coefficient YO2/S of 1.21. The oxygen conversion degree, defined as part of oxygen feed consumed by So oxidation, increased from 0.7% to 68% when the oxygen supply was reduced from 150 to
.
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